Cryptic crossword clue
A Catholic had once represented senior cleric 10

The most common and most likely answer to this crossword clue is the 10 letter word ARCHDEACON

I've seen this crossword clue in Financial Times
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Buddy explains!

The straight part
We know that "senior cleric" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case senior cleric = archdeacon.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does ARCHDEACON mean?

ARCHDEACON noun
  1. In the Anglican and Eastern Orthodox systems, a senior administrative official in a diocese, just under the bishop, often in charge of an archdeaconry. As a title, it can be filled by either a deacon or priest.

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