The most common and most likely answer to this crossword clue is the 7 letter word EYEBATH
I've seen this crossword clue in The Guardian
E
Y
E
B
A
T
H
Buddy explains!
The straight part
We know that "a very small vessel" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case a very small vessel = eyebath.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.
What does EYEBATH mean?
EYEBATH noun- A cup-shaped vessel used to apply eyewash