The most common and most likely answer to this crossword clue is the 10 letter word SKIPPERING
I've seen this crossword clue in The Daily Telegraph
S
K
I
P
P
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R
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N
G
More clues leading to the result SKIPPERING
Buddy explains!
The straight part
We know that "being captain" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case being captain = skippering.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.
What does SKIPPERING mean?
SKIPPERING verb- To captain a ship or a sports team.
- To take shelter in a barn or shed.