Cryptic crossword clue
Appointing an overthrown Lib Dem leader of yesteryear 6

The most common and most likely answer to this crossword clue is the 6 letter word NAMING

I've seen this crossword clue in The Daily Telegraph
N
A
M
I
N
G


Buddy explains!

The straight part
We know that "Appointing" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case appointing = naming.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does NAMING mean?

NAMING verb
  1. (ditransitive) To give a name to.
  2. To mention, specify.
  3. To identify as relevant or important
  4. To publicly implicate.
  5. To designate for a role.
  6. (Westminster system politics) To initiate a process to temporarily remove a member of parliament who is breaking the rules of conduct.
NAMING noun
  1. The process of giving names to things.
  2. A ritual or ceremony in which a person's name is given or announced.
NAMING adjective
  1. Giving a name to a person or thing.

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