Cryptic crossword clue
Aussie building slab forming sphere whenever put up 5

The most common and most likely answer to this crossword clue is the 5 letter word FIBRO

F
I
B
R
O

Buddy explains!

The straight part
We know that "Aussie building slab" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case aussie building slab = fibro.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does FIBRO mean?

FIBRO noun
  1. Fibro-cement; a building material consisting of asbestos fibres and cement pressed into sheets.
  2. Fibromyalgia.

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