Cryptic crossword clue
Between cities and at home, queen wears head garment 10

The most common and most likely answer to this crossword clue is the 10 letter word INTERURBAN

I've seen this crossword clue in The Guardian
I
N
T
E
R
U
R
B
A
N

Buddy explains!

The straight part
We know that "Between cities" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case between cities = interurban.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does INTERURBAN mean?

INTERURBAN noun
  1. A railway carrying mainly passengers between two or more urban centres.
INTERURBAN adjective
  1. Of, pertaining to, involving or joining two or more urban centres

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