The most common and most likely answer to this crossword clue is the 5 plus 6 letter word CATCH TWENTY
I've seen this crossword clue in The Daily Telegraph
C
A
T
C
H
T
W
E
N
T
Y
Buddy explains!
The straight part
We know that "Book" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case book = catch twenty.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.