Cryptic crossword clue
Bun in oven initially jarred when entering state of matrimony 9

The most common and most likely answer to this crossword clue is the 9 letter word CONNUBIAL

I've seen this crossword clue in The Guardian
C
O
N
N
U
B
I
A
L

Buddy explains!

The straight part
We know that "of matrimony/of matrimony" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case of matrimony/of matrimony = connubial.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does CONNUBIAL mean?

CONNUBIAL adjective
  1. Of or relating to the state of being married.

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