The most common and most likely answer to this crossword clue is the 6 plus 8 letter word WARSAW CONCERTO
I've seen this crossword clue in The Daily Telegraph
W
A
R
S
A
W
C
O
N
C
E
R
T
O
Buddy explains!
The straight part
We know that "a piece for piano and orchestra" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case a piece for piano and orchestra = warsaw concerto.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.