Cryptic crossword clue
Cast spell over element in umpteenth rally 8

The most common and most likely answer to this crossword clue is the 8 letter word ENTHRALL

I've seen this crossword clue in The Daily Telegraph
E
N
T
H
R
A
L
L

Buddy explains!

The straight part
We know that "Cast spell over" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case cast spell over = enthrall.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does ENTHRALL mean?

ENTHRALL verb
  1. To hold spellbound; to bewitch, charm or captivate.
  2. To make subservient; to enslave or subjugate.

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