The most common and most likely answer to this crossword clue is the 8 letter word APHELION
I've seen this crossword clue in The Times
A
P
H
E
L
I
O
N
More clues leading to the result APHELION
Buddy explains!
The straight part
We know that "as far from the sun as possible" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case as far from the sun as possible = aphelion.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.
What does APHELION mean?
APHELION noun- The point in the elliptical orbit of a planet, comet, etc., where it is farthest from the Sun.