The most common and most likely answer to this crossword clue is the 5 letter word HATES
H
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The straight part
We know that "he can’t stand" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case he can’t stand = hates.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.
What does HATES mean?
HATES noun- An object of hatred.
- Hatred.
- Negative feedback, abusive behaviour.
- To dislike intensely or greatly.
- To experience hatred.