Cryptic crossword clue
Chilling in Rio, I relaxed with gin and tonic 3-12

The most common and most likely answer to this crossword clue is the 16 letter word AIR-CONDITIONING

I've seen this crossword clue in Independent
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The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does AIR-CONDITIONING mean?

AIR-CONDITIONING noun
  1. The state of temperature and humidity produced by an air conditioner.
  2. An air conditioner or system of air conditioners.
AIR-CONDITIONING verb
  1. To mechanically cool a space or an entire structure.

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