The most common and most likely answer to this crossword clue is the 5 letter word BRAVE
I've seen this crossword clue in The Times
B
R
A
V
E
More clues leading to the result BRAVE
- Face that a woman usually has on a certain day in May?
- Daring Bishop facing rant
- Courageous bishop has wild party
- Splendid bachelor party
- Noble‘s heading for birthday party
- British party weather
- Defy British party
- Underwear with visible edges — that’s audacious
- Courageous Victor breaking into Bank of Scotland
- Endure first part of bachelor party
Buddy explains!

The straight part
We know that "Daring" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case daring = brave.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.
What does BRAVE mean?
BRAVE noun- A Native American warrior.
- A man daring beyond discretion; a bully.
- A challenge; a defiance; bravado.
- To encounter with courage and fortitude, to defy, to provoke.
- To adorn; to make fine or showy.
- Strong in the face of fear; courageous.
- Having any sort of superiority or excellence.
- Making a fine show or display.