The most common and most likely answer to this crossword clue is the 9 letter word CLOISONNE
I've seen this crossword clue in Independent
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The straight part
We know that "Decorative work" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case decorative work = cloisonne.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.
What does CLOISONNE mean?
CLOISONNE noun- (metalwork) A decorative technique for metalwork, especially brass, whereby colored enamel is baked between raised ridges of the metal.
- (metalwork) Objects decorated by this technique collectively.