Cryptic crossword clue
Defying orders, perhaps, fellow learner’s joining expedition 8

The most common and most likely answer to this crossword clue is the 8 letter word FLOUTING

I've seen this crossword clue in The Daily Telegraph
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Buddy explains!

The straight part
We know that "Defying orders, perhaps" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case defying orders, perhaps = flouting.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does FLOUTING mean?

FLOUTING verb
  1. To express contempt for (laws, rules, etc.) by word or action.
  2. To scorn.
FLOUTING noun
  1. The act by which something is flouted.

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