The most common and most likely answer to this crossword clue is the 13 letter word ACCESSIBILITY
I've seen this crossword clue in The Sunday Telegraph
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More clues leading to the result ACCESSIBILITY
Buddy explains!

The straight part
We know that "Ease of understanding" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case ease of understanding = accessibility.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.
Crossword Answer definitions
ACCESSIBILITY noun- The quality of being accessible, or of admitting approach; receptiveness.
- Features that increase software usability for users with certain impairments.