The most common and most likely answer to this crossword clue is the 6 plus 7 letter word INLAND REVENUE
I
N
L
A
N
D
R
E
V
E
N
U
E
More clues leading to the result INLAND REVENUE
Buddy explains!

The straight part
We know that "tax collectors, say" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case tax collectors, say = inland revenue.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.