The most common and most likely answer to this crossword clue is the 8 letter word SUPERNAL
S
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Buddy explains!

The straight part
We know that "Heavenly!" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case heavenly! = supernal.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.
What does SUPERNAL mean?
SUPERNAL adjective- Pertaining to heaven or to the sky; celestial.
- Exalted, exquisite, superlative.