The most common and most likely answer to this crossword clue is the 4 plus 6 letter word FIRE ESCAPE
I've seen this crossword clue in The Daily Telegraph
F
I
R
E
E
S
C
A
P
E
Buddy explains!

The straight part
We know that "a way to avoid danger" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case a way to avoid danger = fire escape.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.