The most common and most likely answer to this crossword clue is the 7 plus 6 letter word TRAFFIC WARDEN
I've seen this crossword clue in The Times
T
R
A
F
F
I
C
W
A
R
D
E
N
More clues leading to the result TRAFFIC WARDEN
Buddy explains!
The straight part
We know that "Fine enforcer ultimately wanted if car wrongly placed?" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case fine enforcer ultimately wanted if car wrongly placed? = traffic warden.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.