Cryptic crossword clue
First cake Alice baked for gluten-intolerant chap 6

The most common and most likely answer to this crossword clue is the 6 letter word CELIAC

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Buddy explains!

The straight part
We know that "gluten-intolerant chap" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case gluten-intolerant chap = celiac.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does CELIAC mean?

CELIAC noun
  1. Someone who has celiac disease.
CELIAC adjective
  1. Of, pertaining to or located within the abdomen or abdominal cavity.
  2. Of or pertaining to celiac disease.

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