The most common and most likely answer to this crossword clue is the 4 plus 4 letter word WELL HEAD
I've seen this crossword clue in Financial Times
W
E
L
L
H
E
A
D
Buddy explains!
The straight part
We know that "First sight of 26" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case first sight of 26 = well head.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.