The most common and most likely answer to this crossword clue is the 12 letter word IMPASSIONATE
I've seen this crossword clue in Financial Times
I
M
P
A
S
S
I
O
N
A
T
E
Buddy explains!
The straight part
We know that "fiery/" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case fiery/ = impassionate.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.