The most common and most likely answer to this crossword clue is the 12 letter word UNASSAILABLE
I've seen this crossword clue in The Times
U
N
A
S
S
A
I
L
A
B
L
E
Buddy explains!

The straight part
We know that "impervious to attack" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case impervious to attack = unassailable.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.
What does UNASSAILABLE mean?
UNASSAILABLE noun- Something, such as a belief, that cannot be assailed.
- Secure against attack; impregnable.
- (by extension) Undeniable, incontestable or incontrovertible.