Cryptic crossword clue
Glassy expression's first seen in very upset suitor 8

The most common and most likely answer to this crossword clue is the 8 letter word VITREOUS

V
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Buddy explains!

The straight part
We know that "Glassy" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case glassy = vitreous.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does VITREOUS mean?

VITREOUS noun
  1. (by elision) The vitreous humor.
VITREOUS adjective
  1. Of or resembling glass; glassy.
  2. Of or relating to the vitreous humor of the eye.
  3. (of ceramics) Having a shiny nonporous surface.
  4. Of a semi-crystalline substance where the atoms exhibit short-range order, but without the long-range order of a crystal.
  5. Positive (of electric charge).

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