Cryptic crossword clue
Gloucester’s opener on nought, first dismissed – certainly won’t appeal! 4

The most common and most likely answer to this crossword clue is the 4 letter word GUCK

G
U
C
K

Buddy explains!

The straight part
We know that "certainly won’t appeal!" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case certainly won’t appeal! = guck.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does GUCK mean?

GUCK noun
  1. The hybrid offspring of a goose and a duck
GUCK noun
  1. An unpleasant sticky substance; goo, gunk.

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