Cryptic crossword clue
Head of Finance probing finer details sorted out elements of pay structure 13

The most common and most likely answer to this crossword clue is the 13 letter word DIFFERENTIALS

I've seen this crossword clue in The Daily Telegraph
D
I
F
F
E
R
E
N
T
I
A
L
S

Buddy explains!

The straight part
We know that "elements of pay structure" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case elements of pay structure = differentials.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does DIFFERENTIALS mean?

DIFFERENTIALS noun
  1. The differential gear in an automobile etc
  2. A qualitative or quantitative difference between similar or comparable things
  3. An infinitesimal change in a variable, or the result of differentiation
  4. One of two coils of conducting wire so related to one another or to a magnet or armature common to both, that one coil produces polar action contrary to that of the other.
  5. A form of conductor used for dividing and distributing the current to a series of electric lamps so as to maintain equal action in all.

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