Cryptic crossword clue
Heading for peak, chap departs wearing guide's climbing equipment 10

The most common and most likely answer to this crossword clue is the 10 letter word STEPLADDER

I've seen this crossword clue in The Times
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Buddy explains!

The straight part
We know that "climbing equipment" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case climbing equipment = stepladder.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does STEPLADDER mean?

STEPLADDER noun
  1. A ladder with steps or treads instead of rungs that is hinged in the middle to form an inverted V, with stays to keep the two halves at a fixed angle.
  2. The player over whom another player marks to take a spectacular mark.

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