Cryptic crossword clue
His Majesty rejected “hot-desking” out of hand, and took the chair 6

The most common and most likely answer to this crossword clue is the 6 letter word HOSTED

H
O
S
T
E
D

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The straight part
We know that "took the chair" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case took the chair = hosted.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does HOSTED mean?

HOSTED verb
  1. To perform the role of a host.
  2. To lodge at an inn.
  3. To run software made available to a remote user or process.

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