Cryptic crossword clue
I accordingly must join legal group on which pressure is constant 6

The most common and most likely answer to this crossword clue is the 6 letter word ISOBAR

I've seen this crossword clue in The Sunday Telegraph
I
S
O
B
A
R


Buddy explains!

The straight part
We know that "on which pressure is constant" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case on which pressure is constant = isobar.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does ISOBAR mean?

ISOBAR noun
  1. A line drawn on a map or chart connecting places of equal or constant pressure.
  2. Either of two nuclides of different elements having the same mass number.
  3. A set of points or conditions at constant pressure.

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