Cryptic crossword clue
I hand Pimms out, one in schooner perhaps 10

The most common and most likely answer to this crossword clue is the 10 letter word MIDSHIPMAN

I've seen this crossword clue in The Daily Telegraph
M
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The straight part
We know that "one in schooner perhaps" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case one in schooner perhaps = midshipman.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does MIDSHIPMAN mean?

MIDSHIPMAN noun
  1. An officer of the lowest rank in several navies; especially, a trainee officer.
  2. A midshipman fish.

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