Cryptic crossword clue
In affair, one desperately pressed one’s suit, perhaps 6

The most common and most likely answer to this crossword clue is the 6 letter word IRONED

I've seen this crossword clue in The Sunday Telegraph
I
R
O
N
E
D


Buddy explains!

The straight part
We know that "pressed one’s suit, perhaps" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case pressed one’s suit, perhaps = ironed.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does IRONED mean?

IRONED verb
  1. To pass an iron over (clothing or some other item made of cloth) in order to remove creases.
  2. To shackle with irons; to fetter or handcuff.
  3. To furnish or arm with iron.

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