The most common and most likely answer to this crossword clue is the 7 plus 3 letter word VINTAGE CAR
I've seen this crossword clue in The Times
V
I
N
T
A
G
E
C
A
R
Buddy explains!

The straight part
We know that "In which to transport quality champagne?" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case in which to transport quality champagne? = vintage car.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.