The most common and most likely answer to this crossword clue is the 9 plus 4 letter word FIRST-AID POST
F
I
R
S
T
-
A
I
D
P
O
S
T
Buddy explains!
The straight part
We know that "emergency care unit" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case emergency care unit = first-aid post.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.