The most common and most likely answer to this crossword clue is the 8 letter word SCHEMERS
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More clues leading to the result SCHEMERS
Buddy explains!

The straight part
We know that "Intriguing people" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case intriguing people = schemers.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.
What does SCHEMERS mean?
SCHEMERS noun- One who plots or schemes, who formulates plans.
- One who is given to scheming.