The most common and most likely answer to this crossword clue is the 13 letter word RE‑ENLISTMENT
I've seen this crossword clue in The Guardian
R
E
â
€
‘
E
N
L
I
S
T
M
E
N
T
Buddy explains!
The straight part
We know that "Joining service again" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case joining service again = re‑enlistment.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.