Cryptic crossword clue
Like the element of chance in roulette usually: hoping, initially, and spinning! 9

The most common and most likely answer to this crossword clue is the 9 letter word SULPHURIC

I've seen this crossword clue in The Times
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Buddy explains!

The straight part
We know that "Like the element" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case like the element = sulphuric.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does SULPHURIC mean?

SULPHURIC adjective
  1. Of, or relating to sulfur, especially in its higher oxidation state

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