Cryptic crossword clue
Maiden having opportunity to discard old slipper 8

The most common and most likely answer to this crossword clue is the 8 letter word MOCCASIN

I've seen this crossword clue in The Guardian
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Buddy explains!

The straight part
We know that "slipper" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case slipper = moccasin.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does MOCCASIN mean?

MOCCASIN noun
  1. A traditional Native North American shoe, usually without a heel or sole, made of a piece of deerskin or other soft leather turned up at the edges which are either stitched together at the top of the shoe, or sewn to a vamp (a piece covering the top of the foot).
  2. A modern shoe with either a low or no heel resembling a traditional Native American moccasin in that the leather forming the sides of the shoe is stitched at the top.
  3. A light beige colour, like that of a moccasin.
  4. Any of several North American snakes of the genus Agkistrodon, particularly the copperhead (Agkistrodon contortrix) and the cottonmouth or water moccasin (Agkistrodon piscivorus).

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