The most common and most likely answer to this crossword clue is the 7 plus 3 letter word DISLEAL (A)
D
I
S
L
E
A
L
(
A
)
Buddy explains!
The straight part
We know that "Hampshire and Kent" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case hampshire and kent = disleal (a).The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.