Cryptic crossword clue
Material collected by Lenin once 5

The most common and most likely answer to this crossword clue is the 5 letter word NINON

I've seen this crossword clue in The Times
N
I
N
O
N


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The straight part
We know that "Material" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case material = ninon.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does NINON mean?

NINON noun
  1. A sheer fabric of silk, rayon, or nylon made in a variety of tight smooth weaves or open lacy patterns.

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