Cryptic crossword clue
Natural extrovert, you said, ultimately seen in nude, is playful 9

The most common and most likely answer to this crossword clue is the 9 letter word UNSTUDIED

I've seen this crossword clue in The Guardian
U
N
S
T
U
D
I
E
D


Buddy explains!

The straight part
We know that "Natural" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case natural = unstudied.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does UNSTUDIED mean?

UNSTUDIED adjective
  1. Free of artifice or cunning; innocent, spontaneous and unaffected.
  2. Not gained by study.
  3. Not studied.

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