The most common and most likely answer to this crossword clue is the 6 letter word OCULUS
O
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The straight part
We know that "round window" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case round window = oculus.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.
What does OCULUS mean?
OCULUS noun- A window or other opening that has an oval or circular shape (as of an eye).