Cryptic crossword clue
Old corsair that's amassed Liberians' first pieces of eight 5

The most common and most likely answer to this crossword clue is the 5 letter word OCTAL

O
C
T
A
L


Buddy explains!

The straight part
We know that "pieces of eight" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case pieces of eight = octal.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does OCTAL mean?

OCTAL noun
  1. The number system that uses the eight digits 0, 1, 2, 3, 4, 5, 6, 7.
  2. A digit or value in the octal number system.
OCTAL adjective
  1. Concerning numbers expressed in octal or mathematical calculations performed using octal.

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