The most common and most likely answer to this crossword clue is the 4 plus 5 letter word ONLY CHILD
I've seen this crossword clue in Financial Times
O
N
L
Y
C
H
I
L
D
Buddy explains!
The straight part
We know that "One ignorant of sibling behaviour" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case one ignorant of sibling behaviour = only child.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.