The most common and most likely answer to this crossword clue is the 5 plus 4 letter word LEGER LINE
I've seen this crossword clue in Financial Times
L
E
G
E
R
L
I
N
E
Buddy explains!

The straight part
We know that "One may be superior to the musical staff" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case one may be superior to the musical staff = leger line.The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.