Cryptic crossword clue
Organic compounds forming chains, perhaps, apart from first time 6

The most common and most likely answer to this crossword clue is the 6 letter word ETHERS

I've seen this crossword clue in The Guardian
E
T
H
E
R
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Buddy explains!

The straight part
We know that "Organic compounds" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case organic compounds = ethers.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does ETHERS mean?

ETHERS noun
  1. The substance formerly supposed to fill the upper regions of the atmosphere above the clouds, in particular as a medium breathed by deities.
  2. Often as aether and more fully as luminiferous aether: a substance once thought to fill all unoccupied space that allowed electromagnetic waves to pass through it and interact with matter, without exerting any resistance to matter or energy; its existence was disproved by the 1887 Michelson–Morley experiment and the theory of relativity propounded by Albert Einstein (1879–1955).
  3. The atmosphere or space as a medium for broadcasting radio and television signals; also, a notional space through which Internet and other digital communications take place; cyberspace.
  4. A particular quality created by or surrounding an object, person, or place; an atmosphere, an aura.
  5. Diethyl ether (C4H10O), an organic compound with a sweet odour used in the past as an anaesthetic.
  6. Any of a class of organic compounds containing an oxygen atom bonded to two hydrocarbon groups.

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