Cryptic crossword clue
Outsize Asian capital’s wanting Liberal made of hard stuff 7

The most common and most likely answer to this crossword clue is the 7 letter word OSSEOUS

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Buddy explains!

The straight part
We know that "made of hard stuff" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case made of hard stuff = osseous.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does OSSEOUS mean?

OSSEOUS adjective
  1. Of, relating to, or made of bone; bony.

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