Cryptic crossword clue
Overanxious people in new union, overwhelmed by carnal desires finally 9

The most common and most likely answer to this crossword clue is the 9 letter word NEUROTICS

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Buddy explains!

The straight part
We know that "Overanxious people" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case overanxious people = neurotics.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does NEUROTICS mean?

NEUROTICS noun
  1. A person who has a neurosis

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