Cryptic crossword clue
Pain suppressant, one for a parentless child, given on purpose 9

The most common and most likely answer to this crossword clue is the 9 letter word ENDORPHIN

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Buddy explains!

The straight part
We know that "Pain suppressant" is the straight/definition part of the clue. The straight part is often a synonym or definition, in this case pain suppressant = endorphin.
The cryptic/wordplay part
In cryptic crossword there's often an wordplay/cryptic part as well.
This part involves a more complex hint, such as an anagram, homophone, hidden word, etc.
Sadly, We don't have an explanation for this specific crossword clue yet.

What does ENDORPHIN mean?

ENDORPHIN noun
  1. Any of a group of peptide hormones found in the brain that act as neurotransmitters and have properties similar to morphine.

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